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Now, you might be wondering, if Na+ is smaller than K+, why can't it just squeeze through the potassium channel? Here's the deal: while Na+ is smaller, it also has a stronger electric field due to its higher charge density. This means that Na+ ions have a stronger attraction to water molecules, forming a tighter hydration shell. The carbonyl oxygen atoms in the selectivity filter of the potassium channel are not positioned in such a way that they can effectively interact with Na+ ions. As a result, Na+ ions would have to shed their water molecules, which requires a lot of energy. This energy barrier prevents Na+ ions from passing through the potassium channel easily.
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